Project 1

Cost-Efficient Direct Recycling for Metal Oxide Cathode Materials

Project Summary

This project, with multiple subprojects, aims to advance an innovative direct recycling and upcycling technique developed by the UoA School of Chemical Engineering and Advanced Materials. This non-destructive approach regenerates spent cathodes while saving the energy and efficiency typically lost in conventional pyro- or hydro-metallurgical methods.

The target customers for this project include battery manufacturers and recyclers seeking to fabricate new cathode materials from spent lithium-ion batteries, as well as electric vehicle manufacturers aiming to meet legislative requirements for battery recycling. The subprojects will address different aspects of the direct recycling process for spent batteries with metal oxide cathodes, focusing on developing efficient, sustainable, and cost-effective methods for recovering and reusing these materials in new batteries.

Prof. Shizhang Qiao

Chief Investigator
Adelaide University

Dr Ebbe Dommisse

Partner Investigator
Iondrive Technologies

Sub-project 1.3

Chemical refurbishment of metal oxide cathodes

Theme 2

Understand battery degradation mechanisms within whole lifecycle. This project will focus on recognizing the phase evolution mechanisms of cathode within whole lifecycles of lithium-ion batteries. Getting a better understanding of the structure failure pathways is crucial to design a restoration pathway to regenerate the black mass more efficiently.

Scalable direct recycling. Aiming at value-added cathode active materials, this task will develop scalable direct recycling methods to regenerate commercial cathode materials, intend to offer recycling solutions to electric vehicles.

Nianji Zhang, PhD

Nianji Zhang

Project Lead | PhD | Adelaide University

Sub-project 1.4

Efficient dual-directional upcycling among varied Ni-content cathodes

Theme 3 + 4

Universal applicability across cathode chemistries. This project leverages a range of spent oxide cathodes, including LiCoO2, NCM111, and NCM811, as precursor materials to produce NCM cathodes with variable nickel contents—33%, 50%, and Ni-rich 60%. This approach covers the most widely used oxide cathode chemistry on the market, enhancing the project’s applicability across diverse cathode types. By offering upcycled cathodes with varied Ni-content, we aim to provide options with different energy densities to better align with customer specifications.

Cost-controllable upcycling process. By addressing the transition metal diffusion as the rate-determining step in the upcycling process for different cathode chemistries, this project employs mechanical ball-milling to break down particles aiming to reduce diffusion distance. A low-cost, efficient solid-state sintering process is then used to reconstruct the layered structure of the final product. We hope to find the optimal process to achieve a balance between cost and performance. This method aims to build a cost-controllable and effective upcycling process for high-performance NCM cathodes.

Dr Zhixiao Xu

Dr Zhixiao Xu

Project Lead | Post-Doctoral Researcher | Adelaide University

Sub-project 1.5

Upcycling of End-of-Life Photovoltaic Waste into Si Anode for High-Performance Li-Ion Batteries

Theme 3

This project focuses on investigating the research strategy for the targeted preparation of high-performance silicon anodes from photovoltaic silicon waste. By optimizing process parameters, an attempt will be made to develop a technical scheme enabling large-scale mass production of silicon anodes with high initial Coulombic efficiency and excellent stability.

It is expected that this process will not only realize the efficient resource utilization of photovoltaic silicon waste but also address the industry-wide challenges of high recycling costs and low added value, while overcoming the core performance bottlenecks of silicon anodes for lithium-ion batteries, such as poor cycling stability and low initial Coulombic efficiency.

This project aims to provide a novel comprehensive technical pathway for resolving the technical pain points in photovoltaic waste recycling and lithium battery material upgrading.

Guangyuan Luo

Guangyuan Luo

Project Lead | PhD | Adelaide University